使用特定任务的离子液体进行选择性电催化氟化。
Use of task-specific ionic liquid for selective electrocatalytic fluorination.
机构信息
Department of Electronic Chemistry, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8502, Japan.
出版信息
Org Lett. 2010 Feb 5;12(3):644-6. doi: 10.1021/ol9028836.
PMID:20050604
Abstract
Highly selective indirect anodic fluorination of organic compounds was successfully carried out for the first time by using a task-specific ionic liquid of iodoarene as a mediator in ionic liquid hydrogen fluoride salts.
摘要
首次成功地使用碘芳烃的特定功能离子液体作为介体在离子液体氟化氢盐中实现了有机化合物的高选择性间接阳极氟化。
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