通过使用手性环戊二烯基钌催化剂的不对称烯丙基取代反应，金属羧酸酯对烯丙基酯的对映选择性合成。
Enantioselective synthesis of allylic esters via asymmetric allylic substitution with metal carboxylates using planar-chiral cyclopentadienyl ruthenium catalysts.
机构信息
Department of Macromolecular Science, Graduate School of Science, Osaka University, Machikaneyama 1-1, Toyonaka, Osaka 560-0043, Japan.
出版信息
J Am Chem Soc. 2010 Feb 3;132(4):1206-7. doi: 10.1021/ja908456b.
PMID:20052978
Abstract
An asymmetric allylic substitution with sodium carboxylate using a planar-chiral cyclopentadienyl ruthenium complex has been developed. Optically active allylic esters were prepared in good yields with high regio- and enantioselectivities.
摘要
已开发出使用平面手性环戊二烯基钌配合物的不对称烯丙基取代与羧酸钠。光学活性烯丙基酯以高区域和对映选择性获得良好的产率制备。
Zotero 插件