手性天然材料β-SnF(2)的金属有机复制品：基于三角和三角双锥配位的手性纯双节点(3,5)-连接网络。
Metal-organic replica of chiral natural material beta-SnF(2): an enantiopure binodal (3,5)-connected net based on triangular and trigonal bipyramidal coordination.
机构信息
Key Laboratory of Polyoxometalates Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, 130024, China.
出版信息
Chem Commun (Camb). 2010 Jan 28;46(4):604-6. doi: 10.1039/b914582f. Epub 2009 Nov 19.
DOI:10.1039/b914582f
PMID:20062876
Abstract
A chiral (3,5)-connected metal-organic framework, based on triangular and trigonal bipyramidal coordiantion, exhibits an unprecedented beta-SnF(2) topology, and represents the first heterocoordinated chiral metal-organic analogue presently known with a natural material topology.
摘要
一种手性（3,5）连接的金属有机骨架，基于三角和三角双锥配位，表现出前所未有的β-SnF2 拓扑结构，并且代表了目前已知的具有天然材料拓扑结构的首例异配位手性金属有机类似物。
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