铀-氢相互作用：三（N，N-二甲基氨基二硼烷）铀（III）的合成与晶体结构。
Uranium-hydrogen interactions: synthesis and crystal structures of tris(N,N-dimethylaminodiboranato)uranium(III).
机构信息
School of Chemical Sciences, University of Illinois at Urbana-Champaign, 600 South Mathews Avenue, Urbana, IL 61801, USA.
出版信息
Chem Commun (Camb). 2010 Jan 21;46(3):407-8. doi: 10.1039/b919490h. Epub 2009 Dec 3.
DOI:10.1039/b919490h
PMID:20066307
Abstract
The reaction of UCl(4) with Na(H(3)BNMe(2)BH(3)) in diethyl ether affords the uranium(III) product U(H(3)BNMe(2)BH(3))(3), which has been crystallized in two different structural isomers depending on the crystallization solvent. Both forms are polymeric, but the nature of the bridging interaction is different in the two forms.
摘要
四氯化铀（UCl(4)）与氢化钠双（频哪醇合）硼（Na(H(3)BNMe(2)BH(3))）在乙醚中的反应生成了三（氢化硼二甲胺合）铀（III）产物 U(H(3)BNMe(2)BH(3))(3)，该产物可根据结晶溶剂的不同结晶出两种不同的结构异构体。两种形式均为聚合物，但两种形式中的桥接相互作用的性质不同。
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