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Crystallographic characterization of (CHSiMe)U(BH).

作者信息

Windorff Cory J, Cross Justin N, Scott Brian L, Kozimor Stosh A, Evans William J

机构信息

Los Alamos National Laboratory, Los Alamos, New Mexico 87544, USA.

Department of Chemistry, University of California, Irvine, California 92697, USA.

出版信息

Acta Crystallogr E Crystallogr Commun. 2021 Mar 12;77(Pt 4):383-389. doi: 10.1107/S2056989021002425. eCollection 2021 Apr 1.

DOI:10.1107/S2056989021002425
PMID:33936762
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8025856/
Abstract

New syntheses have been developed for the synthesis of (borohydrido-κ )tris-[η-(tri-methyl-sil-yl)cyclo-penta-dien-yl]uranium(IV), [U(BH)(CHSi)] or Cp'U(BH) (Cp' = CHSiMe) and its structure has been determined by single-crystal X-ray crystallography. This compound crystallized in the space group and the structure features three -coordinated Cp' rings and a -coordinated (BH) ligand.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da50/8025856/f0739ab65fde/e-77-00383-fig12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da50/8025856/dbbcd64cd19c/e-77-00383-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da50/8025856/d52299a70708/e-77-00383-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da50/8025856/e9975e7b0d00/e-77-00383-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da50/8025856/8a13456a99b4/e-77-00383-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da50/8025856/fb71cc094dbe/e-77-00383-fig5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da50/8025856/ee6aaa0dd978/e-77-00383-fig6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da50/8025856/f6d192d87287/e-77-00383-fig7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da50/8025856/bae99402be59/e-77-00383-fig8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da50/8025856/bb70224bb7d7/e-77-00383-fig9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da50/8025856/aa63aca16605/e-77-00383-fig10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da50/8025856/f7098d8bc04d/e-77-00383-fig11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da50/8025856/f0739ab65fde/e-77-00383-fig12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da50/8025856/dbbcd64cd19c/e-77-00383-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da50/8025856/d52299a70708/e-77-00383-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da50/8025856/e9975e7b0d00/e-77-00383-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da50/8025856/8a13456a99b4/e-77-00383-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da50/8025856/fb71cc094dbe/e-77-00383-fig5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da50/8025856/ee6aaa0dd978/e-77-00383-fig6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da50/8025856/f6d192d87287/e-77-00383-fig7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da50/8025856/bae99402be59/e-77-00383-fig8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da50/8025856/bb70224bb7d7/e-77-00383-fig9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da50/8025856/aa63aca16605/e-77-00383-fig10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da50/8025856/f7098d8bc04d/e-77-00383-fig11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da50/8025856/f0739ab65fde/e-77-00383-fig12.jpg

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