Morimoto K, Murakami Y
Appl Opt. 1969 Jan 1;8 Suppl 1:50-4.
The electrophotographic layer consisting of poly-3,6-dibromo-N-vinylcarbazole was sensitized with twenty-seven kinds of triarylcarbonium salts. The carbonium salt compounds used have the formula: [equation] The novel sensitizers differ in two points from the well-known triphenylmethane dyestuffs sensitizers for the organic electrophotoconductors. First, the triphenylmethane dyestuffs have at least two radicals such as amino or dimethylamino radical. The novel sensitizers have not such a radical. Second, the novel sensitizers have an extreme ability to increase the photosensitivity of organic photoconductors. When the photoconductive polymer sensitized with carbonium salts is applied to semitransparent paper, cellophane papers or plastic sheet, a transparent electrophotographic material can be obtained. These materials are superior to sensitized zinc oxide paper in photosensitivity. Such a transparent material can be used as a master for diazo copy, for overhead projection copy, or for slides.
由聚-3,6-二溴-N-乙烯基咔唑组成的电子照相层用二十七种三芳基碳鎓盐进行了敏化。所使用的碳鎓盐化合物具有如下通式:[方程式] 这种新型敏化剂与用于有机电子照相导体的著名三苯甲烷染料敏化剂在两点上有所不同。第一,三苯甲烷染料具有至少两个如氨基或二甲基氨基这样的基团。而新型敏化剂没有这样的基团。第二,新型敏化剂具有极大提高有机光电导体光敏性的能力。当用碳鎓盐敏化的光电导聚合物应用于半透明纸、玻璃纸或塑料片时,可得到一种透明电子照相材料。这些材料在光敏性方面优于敏化氧化锌纸。这样一种透明材料可用作重氮复印、投影复印或幻灯片的原版。