针对氧还原催化作用，对希夫碱杯[4]吡咯二钴 Pacman 配合物进行定制。
Tailoring dicobalt Pacman complexes of Schiff-base calixpyrroles towards dioxygen reduction catalysis.
机构信息
EaStCHEM School of Chemistry, University of Edinburgh, Joseph Black Building, The King's Buildings, West Mains Road, Edinburgh, UK EH9 3JJ.
出版信息
Chem Commun (Camb). 2010 Feb 7;46(5):710-2. doi: 10.1039/b923189g. Epub 2009 Dec 18.
DOI:10.1039/b923189g
PMID:20087495
Abstract
By modifying the mouth of a macrocyclic dicobalt Pacman complex, it is possible to both isolate new bridging-superoxo and hydroxyl complexes and to tune the reactivity of this system towards catalytic four-electron reduction of dioxygen to water.
摘要
通过修饰大环二钴 Pacman 配合物的口部，可以分离出新型桥联超氧和羟基配合物，并调节该体系对氧气四电子还原为水的催化反应性。
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