芳环-全氟芳环相互作用促进晶体状态下的叠氮化物和炔烃的无铜环加成反应。
Copper-free cycloaddition of azide and alkyne in crystalline state facilitated by arene-perfluoroarene interactions.
机构信息
Beijing National Laboratory for Molecular Sciences (BNLMS), Key Labs of Polymer Chemistry & Physics of Ministry of Education, College of Chemistry, Peking University, Beijing, 100871, China.
出版信息
Chem Commun (Camb). 2010 Feb 7;46(5):782-4. doi: 10.1039/b912337g. Epub 2009 Dec 1.
DOI:10.1039/b912337g
PMID:20087519
Abstract
Facilitated by arene-perfluoroarene interactions, a 1,3-dipolar cycloaddition between azide and alkyne proceeded in the crystals at room temperature in the absence of a copper(I) catalyst, and the reaction was confirmed to be a highly regioselective process giving the 1,4-triazole product.
摘要
在芳环-全氟芳环相互作用的促进下，室温下在无铜（I）催化剂存在的情况下，叠氮化物和炔烃之间发生了 1,3-偶极环加成反应，反应被确认为高度区域选择性过程，生成 1,4-三唑产物。
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