Beijing National Laboratory for Molecular Sciences (BNLMS), Key Labs of Polymer Chemistry & Physics of Ministry of Education, College of Chemistry, Peking University, Beijing, 100871, China.
Chem Commun (Camb). 2010 Feb 7;46(5):782-4. doi: 10.1039/b912337g. Epub 2009 Dec 1.
Facilitated by arene-perfluoroarene interactions, a 1,3-dipolar cycloaddition between azide and alkyne proceeded in the crystals at room temperature in the absence of a copper(I) catalyst, and the reaction was confirmed to be a highly regioselective process giving the 1,4-triazole product.
在芳环-全氟芳环相互作用的促进下，室温下在无铜（I）催化剂存在的情况下，叠氮化物和炔烃之间发生了 1,3-偶极环加成反应，反应被确认为高度区域选择性过程，生成 1,4-三唑产物。
