铂催化的串联 1,2-酰氧基迁移/烯炔酯的分子内 [3 + 2] 环加成反应。
Pt-catalyzed tandem 1,2-acyloxy migration/intramolecular [3 + 2] cycloaddition of enynyl esters.
机构信息
State Key Laboratory of Applied Organic Chemistry, Department of Chemistry, Lanzhou University, Lanzhou 730000, PR China.
出版信息
J Am Chem Soc. 2010 Feb 17;132(6):1788-9. doi: 10.1021/ja910346m.
PMID:20099822
Abstract
A platinum-catalyzed tandem reaction involving enynyl ester isomerization and subsequent intramolecular [3 + 2] cyclization has been developed. This strategy provides an efficient approach to five-, six-, or seven-membered cyclic polyfunctional compounds.
摘要
发展了一种包含炔基酯异构化和随后的分子内[3+2]环化的铂催化串联反应。该策略为五、六或七元环状多官能化合物提供了一种有效的方法。
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