镍催化的烯基和芳基氨基甲酸酯与芳基硼酸频哪醇酯的高效、实用的铃木-宫浦偶联反应。
Nickel-catalyzed efficient and practical Suzuki-Miyaura coupling of alkenyl and aryl carbamates with aryl boroxines.
机构信息
Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Green Chemistry Center, Peking University, Department of Chemistry, Chengdu, Sichuan, China.
出版信息
Org Lett. 2010 Feb 19;12(4):884-7. doi: 10.1021/ol9029534.
PMID:20099867
Abstract
Suzuki-Miyaura coupling of unactivated alkenyl carbamates is described to construct polysubstituted olefins. The developed process is also suitable for heteroaromatic and even electron-rich aromatic carbamates.
摘要
本文描述了 unactivated alkenyl carbamates 的 Suzuki-Miyaura 偶联反应，用于构建多取代烯烃。所开发的方法也适用于杂芳基和富电子的芳香基 carbamates。
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