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用储量丰富的金属催化剂实现（杂）芳基酯与酚的酯交换反应。

Transesterification of (hetero)aryl esters with phenols by an Earth-abundant metal catalyst.

作者信息

Chen Jianxia, Namila E, Bai Chaolumen, Baiyin Menghe, Agula Bao, Bao Yong-Sheng

机构信息

College of Chemistry and Environmental Science, Inner Mongolia Key Laboratory of Green Catalysis, Inner Mongolia Normal University Hohhot 010022 China

出版信息

RSC Adv. 2018 Jul 13;8(44):25168-25176. doi: 10.1039/c8ra04984j. eCollection 2018 Jul 9.

DOI:10.1039/c8ra04984j
PMID:35542121
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9082394/
Abstract

Readily available and inexpensive Earth-abundant alkali metal species are used as efficient catalysts for the transesterification of aryl or heteroaryl esters with phenols which is a challenging and underdeveloped transformation. The simple conditions and the use of heterogeneous alkali metal catalyst make this protocol very environmentally friendly and practical. This reaction fills in the missing part in transesterification reaction of phenols and provides an efficient approach to aryl esters, which are widely used in the synthetic and pharmaceutical industry.

摘要

容易获得且价格低廉的地球上储量丰富的碱金属物种被用作芳基或杂芳基酯与酚进行酯交换反应的高效催化剂，该反应是一项具有挑战性且尚未充分发展的转化反应。简单的反应条件以及非均相碱金属催化剂的使用使得该方法非常环保且实用。该反应填补了酚酯交换反应中缺失的部分，并为芳基酯提供了一种有效方法，芳基酯在合成和制药工业中广泛应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f0aa/9082394/87541eb25d9e/c8ra04984j-s5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f0aa/9082394/1cb367095d95/c8ra04984j-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f0aa/9082394/3f2d46b1ffa9/c8ra04984j-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f0aa/9082394/f46550514e0a/c8ra04984j-s3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f0aa/9082394/b17675db86f8/c8ra04984j-s4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f0aa/9082394/af4aff9394de/c8ra04984j-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f0aa/9082394/87541eb25d9e/c8ra04984j-s5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f0aa/9082394/1cb367095d95/c8ra04984j-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f0aa/9082394/3f2d46b1ffa9/c8ra04984j-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f0aa/9082394/f46550514e0a/c8ra04984j-s3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f0aa/9082394/b17675db86f8/c8ra04984j-s4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f0aa/9082394/af4aff9394de/c8ra04984j-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f0aa/9082394/87541eb25d9e/c8ra04984j-s5.jpg

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本文引用的文献

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