Department of Chemistry, Imperial College London, Exhibition Road, South Kensington, UK.
Dalton Trans. 2010 Feb 7;39(5):1171-5. doi: 10.1039/b918970j. Epub 2009 Dec 7.
Catalytic hydroamination reactions involving the addition of carboxamides (X = CO), carbamates (X = CO(2)) and sulfonamides (X = SO(2)) to unactivated C=C bonds are briefly reviewed. Development in this field of catalytic research is briefly charted, followed by a discussion of possible mechanisms, including arguments to support the operation of both metal and Brønsted acid catalysis in these systems. Future developments in the area are summarised.
简要回顾了涉及酰胺（X = CO）、氨基甲酸酯（X = CO（2））和磺酰胺（X = SO（2））加成到未活化的 C=C 键的催化氢胺化反应。简要概述了催化研究领域的发展情况，然后讨论了可能的机制，包括支持这些体系中金属和布朗斯台德酸催化作用的论点。总结了该领域的未来发展。
