通过均相和非均相催化由硫醇和醇制备硫醚。
Access to thioethers from thiols and alcohols via homogeneous and heterogeneous catalysis.
作者信息
Markwitz Martyna, Labrzycki Klaudiusz, Azcune Laura, Landa Aitor, Kuciński Krzysztof
机构信息
Faculty of Chemistry, Adam Mickiewicz University, Uniwersytetu Poznanskiego St. 8, 61-614, Poznan, Poland.
Department of Organic Chemistry I, Faculty of Chemistry, University of the Basque Country UPV/EHU, Paseo Manuel Lardizábal 3, 20018, San Sebastián, Spain.
出版信息
Sci Rep. 2023 Nov 23;13(1):20624. doi: 10.1038/s41598-023-47938-4.
A metal-free dehydrative thioetherification method has been reported, enabling the conversion of various alcohols and thiols into thioethers. By employing triflic acid as a catalyst or utilizing a recyclable NAFION® superacid catalyst, these methods significantly improve the efficiency and practicality of sulfide preparation.
已报道了一种无金属脱水硫醚化方法，可将各种醇和硫醇转化为硫醚。通过使用三氟甲磺酸作为催化剂或利用可回收的NAFION®超强酸催化剂，这些方法显著提高了硫化物制备的效率和实用性。
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