非相邻双四氢呋喃和非相邻四氢呋喃-四氢吡喃亚类番荔枝烷型乙酰基生物合成。
Total synthesis of annonaceous acetogenins belonging to the non-adjacent bis-THF and non-adjacent THF-THP sub-classes.
机构信息
The School of Chemistry, The University of Southampton, Highfield, Southampton SO171BJ, UK.
出版信息
Molecules. 2010 Jan 21;15(1):460-501. doi: 10.3390/molecules15010460.
Abstract
The synthesis of the subgroups of acetogenins containing non-adjacent bis-THF and non-adjacent THF-THP core units is reviewed. Specifically, total syntheses of gigantecin, 4-deoxygigantecin, cis-sylvaticin, squamostatin-C, squamostatin-D, sylvaticin and mucocin are discussed.
摘要
本文综述了含有非相邻双-THF 和非相邻 THF-THP 核单元的乙酰二萜类化合物亚组的合成。具体讨论了 gigantecin、4-去氧 gigantecin、cis-sylvaticin、squamostatin-C、squamostatin-D、sylvaticin 和 mucocin 的全合成。
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