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介质阻挡放电中农药厂恶臭气体的去除。

Abatement of malodorants from pesticide factory in dielectric barrier discharges.

机构信息

Institute of Industrial Ecology and Environment, Zhejiang University (Yuquan Campus) Hangzhou 310027, PR China.

出版信息

J Hazard Mater. 2010 May 15;177(1-3):908-13. doi: 10.1016/j.jhazmat.2010.01.002. Epub 2010 Jan 11.

Abstract

Traditional odor control methods are limitative technically and economically for the abatement of odor from pesticide factory due to its toxicity and complicated composition. Non-thermal plasma (NTP) methods, typically characterized by high removal efficiency, energy yields and good economy, offer possible alternative solutions. This paper provides laboratory scale experimental data on the removal of simulated odors from pesticide factory with various humidity (0-0.8 vol%) and oxygen contents (0-21%) by a dielectric barrier discharge (DBD) reactor. Peak voltage and initial dimethylamine (DML) concentration are important factors that influence the DML removal efficiency and energy yield. The conversion of DML of 761 mg/m(3) reaches 100% at a peak voltage of 41.25 kV. Under the experiment conditions, the conversion of DML increases with an increase of oxygen contents. And the highest DML conversion was achieved with the gas stream containing 0.3% water. Simultaneously, the concentration of O(3) and OH radical in reactor was measured. Higher conversion, higher energy yield and fewer byproducts were found in mixed odor (DML+dimethyl sulfide (DMS)) treatment than that in single odor treatment. The energy yield is promoted from 2.13 to 5.20mg/kJ.

摘要

由于毒性和复杂的成分,传统的气味控制方法在农药厂的气味减排方面在技术和经济上受到限制。非热等离子体(NTP)方法通常具有高效率、高能量产出和良好的经济性,为可能的替代解决方案提供了可能。本文提供了实验室规模的实验数据,研究了介电阻挡放电(DBD)反应器在各种湿度(0-0.8 体积%)和氧气含量(0-21%)下从农药厂模拟气味中去除的情况。峰值电压和初始二甲胺(DML)浓度是影响 DML 去除效率和能量产出的重要因素。在 41.25 kV 的峰值电压下,761 mg/m(3)的 DML 转化率达到 100%。在实验条件下,DML 的转化率随着氧气含量的增加而增加。并且在含有 0.3%水的气流中,DML 的转化率最高。同时,测量了反应器中 O(3)和 OH 自由基的浓度。在处理混合气味(DML+二甲硫醚(DMS))时,发现转化率、能量产出和副产物都比单一气味处理时更高。能量产出从 2.13 提高到 5.20mg/kJ。

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