Institute of Environment Science & Engineering, Hangzhou Dianzi University, Hangzhou 310018, PR China.
Chemosphere. 2013 Jul;92(6):725-30. doi: 10.1016/j.chemosphere.2013.04.014. Epub 2013 May 3.
The dielectric barrier discharge (DBD) regeneration process of an activated carbon (AC) saturated with dimethyl sulfide was studied on a laboratory scale. The results showed sustainable high regeneration efficiency (RE) (>90%) in successive regeneration cycles (10 cycles). Energy density, humidity and oxygen content were key factors for DBD system, with optimum conditions of 761JL(-1), 0-1vol% and 5%, respectively. The high efficiency was likely attributed to the improvement of structure and surface properties of AC by DBD. After the first regeneration, surface area, micropore volume and total pore volume of AC increased by 8%, 23% and 15% respectively, while average pore size decreased by 9.5%. The number of carboxylic groups doubled (from 0.22 to 0.48mmolg(-1)) while that of phenolic groups remarkably decreased (from 0.48 to 0.26mmolg(-1)) after successive regeneration cycles, which helped to maintain high RE. The results suggested DBD as a novel, efficient alternative process for odor-saturated AC regeneration.
采用实验室规模研究了介电阻挡放电(DBD)对二甲基硫饱和活性炭(AC)的再生过程。结果表明,在连续的再生循环(10 个循环)中,可持续实现高再生效率(RE)(>90%)。能量密度、湿度和氧气含量是 DBD 系统的关键因素,其最佳条件分别为 761JL(-1)、0-1vol%和 5%。高效率可能归因于 DBD 改善了 AC 的结构和表面性能。在第一次再生后,AC 的比表面积、微孔体积和总孔体积分别增加了 8%、23%和 15%,而平均孔径减小了 9.5%。再生循环后,羧基数量增加了一倍(从 0.22 增加到 0.48mmol/g),而酚基数量显著减少(从 0.48 减少到 0.26mmol/g),这有助于保持高 RE。结果表明,DBD 是一种新型的、高效的替代工艺,可用于再生有气味的饱和 AC。