State Key Laboratory of High Performance Ceramics and Superfine Microstructures, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Dingxi Road, Shanghai 200050, PR China.
J Hazard Mater. 2010 May 15;177(1-3):1013-8. doi: 10.1016/j.jhazmat.2010.01.020. Epub 2010 Jan 11.
Visible-light-induced Bi(2)WO(6) photocatalyst has been successfully synthesized via a facile low-temperature combustion synthesis method, using glycine as the fuel. The photocatalytic activities of the as-synthesized samples were evaluated by the photodegradation of rhodamine B (RhB) and phenol under visible-light irradiation (lambda>420 nm). The results showed that the molar ratio of fuel to oxidizer had an important influence on the photocatalytic activities of the products. When the molar ratio of fuel to oxidizer was 1, the photocatalyst exhibited the highest degradation efficiency, which can completely degrade RhB with a concentration up to 10(-4)M within 75 min. Besides decoloring, the markable reduction of chemical oxygen demand (COD) was also observed in the degradation of RhB, further demonstrating the photocatalytic performance of Bi(2)WO(6). Additionally, the photocatalyst showed much enhanced visible photocatalytic efficiency, up to 94.2% in 4h, than the bulk Bi(2)WO(6) powder (SSR) in the degradation of phenol.
采用简单的低温燃烧合成法,以甘氨酸为燃料,成功合成了可见光照诱导的 Bi(2)WO(6)光催化剂。通过可见光照下罗丹明 B(RhB)和苯酚的光降解评价了所得样品的光催化活性。结果表明,燃料与氧化剂的摩尔比对产物的光催化活性有重要影响。当燃料与氧化剂的摩尔比为 1 时,光催化剂表现出最高的降解效率,可在 75 分钟内完全降解浓度高达 10(-4)M 的 RhB。除了脱色外,在 RhB 的降解过程中还观察到化学需氧量(COD)的显著降低,进一步证明了 Bi(2)WO(6)的光催化性能。此外,与体相 Bi(2)WO(6)粉末(SSR)相比,该光催化剂在苯酚降解中表现出更高的可见光光催化效率,在 4 小时内达到 94.2%。