氯化亚铜/四氯化碳促进的叔胺与磺酰叠氮化合物方便合成磺酰基脒。
CuCl/CCl(4)-promoted convenient synthesis of sulfonyl amidines from tertiary amines and sulfonyl azides.
机构信息
Institute of Industrial Catalysis, College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310014, People's Republic of China.
出版信息
Org Lett. 2010 Mar 5;12(5):897-9. doi: 10.1021/ol1000236.
PMID:20121255
Abstract
Promoted by CuCl/CCl(4), a variety of sulfonyl azides and tertiary amines were successfully coupled to give sulfonyl amidine derivatives in good to excellent yields. A possible mechanism for this reaction is discussed.
摘要
在 CuCl/CCl(4) 的促进下，各种磺酰基叠氮化物和叔胺成功地偶联，以良好至优异的收率得到磺酰基脒衍生物。讨论了该反应的可能机理。
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