Sherman Eric S, Chemler Sherry R
The University at Buffalo, The State University of New York, Buffalo, New York 14260, USA, ; e-mail:
Adv Synth Catal. 2009 Feb 1;351(3):467. doi: 10.1002/adsc.200800705.
The scope of the intramolecular copper(II)-catalyzed carboamination and aminooxygenation reactions of olefins has been extended to include N-aryl-2-allylanilines. These substrates exhibit divergent reactivity under catalytic vs. stoichiometric conditions.
分子内铜(II)催化的烯烃碳胺化和氨氧化反应的范围已扩展至包括N-芳基-2-烯丙基苯胺。这些底物在催化条件与化学计量条件下表现出不同的反应活性。