Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan.
Chem Commun (Camb). 2010 Feb 21;46(7):1029-31. doi: 10.1039/b915722k. Epub 2009 Dec 1.
Metalation of a bis(N(2)O(2)) macrocyclic ligand 1 with nickel(II) acetate afforded a dinuclear metallohost 2, resulting in a significant enhancement of recognition ability of alkali metal ions and the promotion of self-aggregation.
用醋酸镍对双(N(2)O(2))大环配体 1 进行金属化,得到双核金属主体 2,这显著增强了对碱金属离子的识别能力,并促进了自组装。