高区域和立体选择性的分子间串联反应合成氯取代的 1,3-丁二烯。
Highly regio- and stereoselective intermolecular tandem reaction to synthesize chloro-substituted 1,3-butadienes.
机构信息
School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, Guangdong, 510640, China.
出版信息
Chem Commun (Camb). 2010 Feb 21;46(7):1035-7. doi: 10.1039/b923464k. Epub 2010 Jan 14.
DOI:10.1039/b923464k
PMID:20126704
Abstract
A palladium catalyzed highly regio- and stereoselective intermolecular tandem reaction of alkynes, CuCl(2) and alkenes by a sequence of chloropalladation/Heck reaction to produce chloro-substituted 1,3-dienes is achieved.
摘要
钯催化的炔烃、CuCl(2)和烯烃的高区域和立体选择性的分子间串联反应，通过氯钯化/Heck 反应的序列实现，生成氯取代的 1,3-二烯。
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