College of Chemistry, University of California, Berkeley, California 94720-1460, USA.
J Am Chem Soc. 2010 Mar 3;132(8):2570-2. doi: 10.1021/ja9104842.
We report a versatile and scalable synthesis of a water-dispersible modular star polymer platform with an enzyme-inspired hydrophobic interior. The cores of the stars can be functionalized at will, independently from the modification of the polymer structure. We explored the use of this material for the creation of a local hydrophobic solvent environment in water and for site isolation of incompatible catalytic entities.
我们报告了一种多功能且可扩展的水散模块星形聚合物平台的合成方法，该平台具有受酶启发的疏水性内部。星形聚合物的核心可以根据需要进行功能化，而无需改变聚合物结构。我们探索了该材料在水中创建局部疏水性溶剂环境以及对不相容催化实体进行位点隔离的用途。
