Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, P.R. China.
Chemistry. 2010 Mar 15;16(11):3497-503. doi: 10.1002/chem.200902799.
Micro/nanoscale magnesium silicate hollow spheres were synthesized by using silica colloidal spheres as a chemical template in one pot. The hollow spherical structure, consisting of well-separated nanoscale units, was microscale as a whole and could be easily handled in solution. The as-synthesized magnesium silicate hollow spheres with large specific surface area showed availability for the removal of organic and heavy-metal ions efficiently from waste water. Importantly, the micro/nanoscale magnesium silicate hollow spheres that had adsorbed organic pollutants could be regenerated by calcination and used repeatedly in pollutant removal. Magnesium silicate hollow spheres synthesized by a scaled-up chemical template method may have potential applications in removing cationic dyes and heavy-metal ions from waste water.
采用硅溶胶作为化学模板,一锅法合成了具有核壳结构的微米/纳米级硅酸镁空心球。这种空心球结构由尺寸均一的纳米级单元组成,整体呈现出微米级尺寸,在溶液中易于操作。所得硅酸镁空心球具有较大的比表面积,可有效地去除废水中的有机污染物和重金属离子。重要的是,吸附了有机污染物的微/纳级硅酸镁空心球可以通过煅烧再生,并可重复用于污染物的去除。采用放大的化学模板法合成的硅酸镁空心球在去除废水中的阳离子染料和重金属离子方面具有潜在的应用前景。