Department of Chemistry University of St Andrews, North Haugh, St Andrews, Fife, KY16 9ST, United Kingdom.
Inorg Chem. 2010 Mar 15;49(6):3064-9. doi: 10.1021/ic1000107.
A series of 5-alkyl/aryl-1,3lambda(4)delta(2),2,4,5-dithiadiazarsoles RAs(S(2)N(2)) (R = Me, Et, (i)Pr, (t)Bu, Ph, Mes) were prepared by a ligand exchange between (n)Bu(2)Sn(S(2)N(2)) and the corresponding organodihalogenoarsines RAsX(2) (X = Cl, I). All products were characterized by NMR, IR, and Raman spectroscopies and mass spectrometry. The crystal structures of the aryldithiadiazarsoles (R = Ph, Mes) were determined.
一系列 5-烷基/芳基-1,3lambda(4)delta(2),2,4,5-二硫代二氮杂环戊二烯 RA(S(2)N(2))（R = Me, Et, (i)Pr, (t)Bu, Ph, Mes）是通过 (n)Bu(2)Sn(S(2)N(2)) 和相应的有机二卤化砷 RAsX(2)（X = Cl, I）之间的配体交换制备的。所有产物均通过 NMR、IR 和拉曼光谱以及质谱进行了表征。芳基二硫代二氮杂环戊二烯的晶体结构（R = Ph, Mes）已被确定。
