神经营养天然产物卡里拉诺木兰醇和克劳瓦诺木兰醇的仿生合成。
Biomimetic syntheses of the neurotrophic natural products caryolanemagnolol and clovanemagnolol.
机构信息
Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station, Austin Texas 78712, USA.
出版信息
Org Lett. 2010 Mar 19;12(6):1304-7. doi: 10.1021/ol100214x.
PMID:20158263
Abstract
Separate short and modular syntheses of the isomeric natural products caryolanemagnolol and clovanemagnolol have been achieved starting from commercially available (-)-caryophyllene. The postulated biosynthetic pathways guided the syntheses of the neuroregenerative small molecules allowing their assembly in as few as two steps.
摘要
已分别采用短程和模块化合成方法，从商业可得的（-）-石竹烯起始，合成出了结构异构体天然产物石竹烯醇和克拉烷醇。假定的生物合成途径指导了神经再生小分子的合成，使它们的组装过程仅需两步。
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