在存在水相葡萄糖的情况下，对银纳米立方体上烷硫醇单分子层分子结构的表面增强拉曼光谱研究。
A SERS study of the molecular structure of alkanethiol monolayers on Ag nanocubes in the presence of aqueous glucose.
作者信息
Rycenga Matthew, McLellan Joseph M, Xia Younan
机构信息
Department of Biomedical Engineering, Washington University, St. Louis, Missouri 63130.
出版信息
Chem Phys Lett. 2009 Sep 22;463(1-3):166-171. doi: 10.1016/j.cplett.2008.08.062.
Abstract
We report progress towards the surface-enhanced Raman scattering (SERS) characterization of self-assembled monolayers (SAMs) on uniform Ag nanocubes. This study quantifies changes in the SAMs induced by the presence of aqueous glucose. The SAMs were prepared from dodecanethiol and they were representative of highly ordered monolayers as indicated by SERS analysis. We examined the SAMs response to glucose and observed conformational changes in the alkanethiolate SAMs. Analysis of the trans and gauche bands as well as the C-H stretching modes of the SAMs suggest that the analyte-SAM interactions were superficial and there was no penetration for the glucose molecules into the monolayers.
摘要
我们报告了在均匀银纳米立方体上对自组装单分子层（SAMs）进行表面增强拉曼散射（SERS）表征的进展。本研究量化了水相葡萄糖的存在对SAMs所引起的变化。这些SAMs由十二烷硫醇制备而成，如SERS分析所示，它们代表了高度有序的单分子层。我们研究了SAMs对葡萄糖的响应，并观察到链烷硫醇盐SAMs的构象变化。对SAMs的反式和顺式带以及C-H伸缩模式的分析表明，分析物与SAMs之间的相互作用是表面性的，葡萄糖分子没有渗透到单分子层中。
相似文献
1
A SERS study of the molecular structure of alkanethiol monolayers on Ag nanocubes in the presence of aqueous glucose.在存在水相葡萄糖的情况下，对银纳米立方体上烷硫醇单分子层分子结构的表面增强拉曼光谱研究。
Chem Phys Lett. 2009 Sep 22;463(1-3):166-171. doi: 10.1016/j.cplett.2008.08.062.
2
Surface-coverage dependence of surface-enhanced raman scattering from gold nanocubes on self-assembled monolayers of analyte.金纳米立方体表面增强拉曼散射对分析物自组装单分子层的表面覆盖度依赖性
J Phys Chem A. 2009 Apr 23;113(16):3973-8. doi: 10.1021/jp810329j.
3
Multiplexing with SERS labels using mixed SAMs of Raman reporter molecules.使用拉曼报告分子的混合自组装单分子层进行表面增强拉曼散射（SERS）标记的多重检测。
Anal Bioanal Chem. 2009 Aug;394(7):1839-44. doi: 10.1007/s00216-009-2868-8. Epub 2009 Jun 19.
4
Tracking down the origin of peculiar vibrational spectra of aromatic self-assembled thiolate monolayers.追踪芳香族自组装硫醇单层独特振动光谱的起源。
Phys Chem Chem Phys. 2018 Dec 5;20(47):29918-29930. doi: 10.1039/c8cp03651a.
5
Binary Monolayers Formed from the Sequential Adsorption of Terphenylthiol and Dodecanethiol on Gold.由三联苯硫醇和十二烷硫醇在金表面依次吸附形成的二元单层膜。
J Phys Chem C Nanomater Interfaces. 2025 May 19;129(21):9844-9856. doi: 10.1021/acs.jpcc.5c00571. eCollection 2025 May 29.
6
Structures and displacement of 1-adamantanethiol self-assembled monolayers on Au{111}.1-金刚烷硫醇在Au{111}上自组装单分子层的结构与位移
J Am Chem Soc. 2005 Jun 22;127(24):8697-704. doi: 10.1021/ja042621o.
7
Self-assembled monolayers of bimetallic Au/Ag nanospheres with superior surface-enhanced Raman scattering activity for ultra-sensitive triphenylmethane dyes detection.具有卓越表面增强拉曼散射活性的双金属金/银纳米球自组装单分子层用于超灵敏三苯甲烷染料检测。
Opt Lett. 2018 Feb 15;43(4):635-638. doi: 10.1364/OL.43.000635.
8
Superhydrophobic surface-enhanced Raman scattering platform fabricated by assembly of Ag nanocubes for trace molecular sensing.通过组装 Ag 纳米立方体制备的超疏水表面增强拉曼散射平台用于痕量分子传感。
ACS Appl Mater Interfaces. 2013 Nov 13;5(21):11409-18. doi: 10.1021/am403655g. Epub 2013 Nov 1.
9
Surface enhanced Raman scattering of p-aminothiophenol self-assembled monolayers in sandwich structure fabricated on glass.在玻璃上制备的三明治结构中对氨基苯硫酚自组装单分子层的表面增强拉曼散射
J Chem Phys. 2006 Feb 21;124(7):74709. doi: 10.1063/1.2172591.
10
Self-assembled alkanethiol monolayers on gold surfaces: resolving the complex structure at the interface by STM.金表面自组装的链烷硫醇单分子层：通过扫描隧道显微镜解析界面处的复杂结构。
Phys Chem Chem Phys. 2014 Sep 28;16(36):19074-90. doi: 10.1039/c4cp00596a.
引用本文的文献
1
Surface-enhanced Raman scattering used to study the structure of layers formed on metal surfaces from single-stranded DNA and 6-mercaptohexan-1-ol: influence of hybridization with the complementary DNA and influence of the metal substrate.表面增强拉曼散射用于研究由单链DNA和6-巯基己醇在金属表面形成的层结构：与互补DNA杂交的影响及金属基底的影响。
RSC Adv. 2022 Dec 8;12(54):35192-35198. doi: 10.1039/d2ra05318g. eCollection 2022 Dec 6.
2
Effects of Conformational Variation on Structural Insights from Solution-Phase Surface-Enhanced Raman Spectroscopy.构象变化对溶液相表面增强拉曼光谱结构见解的影响。
J Phys Chem B. 2021 Mar 4;125(8):2031-2041. doi: 10.1021/acs.jpcb.0c10576. Epub 2021 Feb 22.
3
Surface Plasmon Resonance, Formation Mechanism, and Surface Enhanced Raman Spectroscopy of Ag-Stained Gold Nanoparticles.银染色金纳米颗粒的表面等离子体共振、形成机制及表面增强拉曼光谱
Front Chem. 2019 Feb 14;7:27. doi: 10.3389/fchem.2019.00027. eCollection 2019.
4
Online Liquid Chromatography-Sheath-Flow Surface Enhanced Raman Detection of Phosphorylated Carbohydrates.在线液相色谱-鞘流表面增强拉曼检测磷酸化碳水化合物。
Anal Chem. 2018 Sep 18;90(18):11062-11069. doi: 10.1021/acs.analchem.8b02907. Epub 2018 Aug 29.
5
Sustained and Cost Effective Silver Substrate for Surface Enhanced Raman Spectroscopy Based Biosensing.基于表面增强拉曼光谱的生物传感用持久且经济有效的银基底。
Sci Rep. 2017 Jul 31;7(1):6917. doi: 10.1038/s41598-017-07186-9.
6
Hierarchical zwitterionic modification of a SERS substrate enables real-time drug monitoring in blood plasma.层状两性离子修饰的 SERS 基底可实现血浆中药物的实时监测。
Nat Commun. 2016 Nov 11;7:13437. doi: 10.1038/ncomms13437.
7
Online SERS detection and characterization of eight biologically-active peptides separated by capillary zone electrophoresis.通过毛细管区带电泳分离的八种生物活性肽的在线表面增强拉曼光谱检测与表征
Analyst. 2015 Mar 7;140(5):1516-22. doi: 10.1039/c4an01980f. Epub 2015 Jan 19.
8
Online SERS detection of the 20 proteinogenic L-amino acids separated by capillary zone electrophoresis.通过毛细管区带电泳分离的20种蛋白质原性L-氨基酸的在线表面增强拉曼光谱检测。
Analyst. 2014 Nov 21;139(22):5989-98. doi: 10.1039/c4an01177e.
9
Direct optical detection of viral nucleoprotein binding to an anti-influenza aptamer.直接光学检测病毒核蛋白与抗流感适体的结合。
Anal Chem. 2012 Jul 3;84(13):5501-8. doi: 10.1021/ac202427e. Epub 2012 Jun 11.
10
Replacement of Poly(vinyl pyrrolidone) by Thiols: A Systematic Study of Ag Nanocube Functionalization by Surface-Enhanced Raman Scattering.用硫醇取代聚乙烯吡咯烷酮：通过表面增强拉曼散射对银纳米立方体功能化的系统研究。
J Phys Chem C Nanomater Interfaces. 2011 Nov 10;115(44):21852-21857. doi: 10.1021/jp207868a.
本文引用的文献
1
Quantitative Correlation of Raman Spectral Indicators in Determining Conformational Order in Alkyl Chains.拉曼光谱指标在确定烷基链构象有序性中的定量相关性
J Phys Chem A. 2002 Aug 1;106(30):6991-6998. doi: 10.1021/jp014311n.
2
Rapid synthesis of small silver nanocubes by mediating polyol reduction with a trace amount of sodium sulfide or sodium hydrosulfide.通过用痕量硫化钠或硫氢化钠介导多元醇还原快速合成小银纳米立方体。
Chem Phys Lett. 2006 Dec 11;432(4-6):491-496. doi: 10.1016/j.cplett.2006.10.095.
3
Spectroscopically enhancing electrical nanotraps.光谱增强电纳米陷阱。
Angew Chem Int Ed Engl. 2008;47(10):1938-41. doi: 10.1002/anie.200705312.
4
Facile synthesis of Ag nanocubes and Au nanocages.银纳米立方体和金纳米笼的简便合成
Nat Protoc. 2007;2(9):2182-90. doi: 10.1038/nprot.2007.326.
5
Temperature-induced conformational changes in human tearlipids hydrocarbon chains.温度诱导的人泪液脂质烃链构象变化。
Biopolymers. 2007;87(2-3):124-33. doi: 10.1002/bip.20798.
6
Divalent metal nanoparticles.二价金属纳米颗粒
Science. 2007 Jan 19;315(5810):358-61. doi: 10.1126/science.1133162.
7
Raman spectra of biological samples: A study of preprocessing methods.生物样品的拉曼光谱：预处理方法研究
Appl Spectrosc. 2006 Dec;60(12):1358-67. doi: 10.1366/000370206779321454.
8
Designing, fabricating, and imaging Raman hot spots.设计、制造和成像拉曼热点。
Proc Natl Acad Sci U S A. 2006 Sep 5;103(36):13300-3. doi: 10.1073/pnas.0605889103. Epub 2006 Aug 24.
9
Loosely packed hydroxyl-terminated SAMs on gold.金表面松散堆积的羟基封端自组装单分子层
Langmuir. 2006 Aug 15;22(17):7235-40. doi: 10.1021/la0531650.
10
Ultrastable substrates for surface-enhanced Raman spectroscopy: Al2O3 overlayers fabricated by atomic layer deposition yield improved anthrax biomarker detection.用于表面增强拉曼光谱的超稳定基底：通过原子层沉积制备的Al2O3覆盖层可提高炭疽生物标志物检测效果。
J Am Chem Soc. 2006 Aug 9;128(31):10304-9. doi: 10.1021/ja0638760.
Zotero 插件