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Stereoselective Synthesis of Cyclometalated Iridium (III) Complexes: Characterization and Photophysical Properties.

作者信息

Yang Liangru, von Zelewsky Alex, Nguyen Huong P, Muller Gilles, Labat Gaël, Stoeckli-Evans Helen

机构信息

School of Chemistry and Chemical Engineering, He'nan University of Technology, 450001 He'nan, P. R. China.

出版信息

Inorganica Chim Acta. 2009 Aug 1;362(10):3853-3856. doi: 10.1016/j.ica.2008.10.011.

Abstract

The stereoselective synthesis of a highly luminescent neutral Ir(III) complex comprising two bidentate chiral, cyclometalating phenylpyridine derivatives, and one acetylacetonate as ligands is described. The final complex and some intermediates were characterized by X-ray structural analysis, NMR-, CD-, and CPL-spectroscopy.

摘要

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本文引用的文献

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Novel HEXOL-type cyclometallated iridium(III) complexes: stereoselective synthesis and structure elucidation.
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Chiral "metallo-spiralenes": helical molecules conformationally stabilised by an organometallic scaffold.
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