Yang Baiyuan, Miller Marvin J
Department of Chemistry and Biochemistry, 251 Nieuwland Science Hall, University of Notre Dame, Notre Dame, IN 46556, United States.
Tetrahedron Lett. 2010 Jan 13;51(2):328-331. doi: 10.1016/j.tetlet.2009.11.015.
Ene reactions of iminonitroso agents with olefins were investigated in both solution and solid phase. Reactions afforded allyl hydroxylamine products in up to 99% yield and with high regioselectivity. A Cu(I)-mediated enantioselective nitroso ene reaction gave an ene product with up to 40% ee.
研究了亚胺基亚硝基试剂与烯烃在溶液和固相中的烯反应。反应得到的烯丙基羟胺产物产率高达99%，且具有高区域选择性。铜（I）介导的对映选择性亚硝基烯反应得到的烯产物对映体过量值（ee）高达40%。
