Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433, P. R. China.
Chem Commun (Camb). 2010 Mar 7;46(9):1553-5. doi: 10.1039/b922662a. Epub 2010 Jan 28.
Chemoselective reduction of alpha,beta-unsaturated aldehydes in the presence of CO and H(2)O proceeds effectively over a ceria-supported gold catalyst system, providing a novel, efficient and clean approach to produce useful primary allyl alcohols with excellent activity and selectivity.
在 CO 和 H(2)O 的存在下,铈负载金催化剂体系可有效地实现α,β-不饱和醛的化学选择性还原,为生产具有优异活性和选择性的有用的伯烯丙醇提供了一种新颖、高效和清洁的方法。