在温和条件下通过高选择性加氢快速合成不饱和醇。
Rapid synthesis of unsaturated alcohols under mild conditions by highly selective hydrogenation.
机构信息
Graduate School of Engineering, Tohoku University, Aoba 6-6-07, Aramaki, Sendai, 980-8579, Japan.
出版信息
Chem Commun (Camb). 2013 Aug 14;49(63):7034-6. doi: 10.1039/c3cc41526k.
PMID:23689498
Abstract
Ir-ReOx/SiO2 acted as a highly active and selective heterogeneous catalyst for the hydrogenation of unsaturated aldehydes to unsaturated alcohols in water at low H2 pressure (0.8 MPa) and low temperature (303 K). The catalysis is derived from the synergy between Ir metal and ReOx.
摘要
Ir-ReOx/SiO2 在低氢压（0.8 MPa）和低温（303 K）条件下，于水中将不饱和醛高效且选择性地催化氢化生成不饱和醇，是一种高活性和选择性的多相催化剂。该催化作用源自 Ir 金属和 ReOx 之间的协同作用。
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