Department of Chemistry, University of Central Florida, P. O. Box 162366, Orlando, FL 32816-2366, USA.
Chemistry. 2010 Mar 15;16(11):3504-9. doi: 10.1002/chem.200902286.
Herein we report on the full experimental measurement of the two-photon absorption circular dichroism spectra of (S)-(-)-1,1'-bi(2-naphthol) and (R)-(+)-1,1'-bi(2-naphthol), their analysis, and theoretical support. The finding of new nonlinear optical fingerprints in chiral molecules offers new opportunities in the recognition and understanding of optically active systems in regions where CD could present strong limitations.
在此,我们报告了(S)-(-)-1,1'-联萘酚和(R)-(+)-1,1'-联萘酚的双光子吸收圆二色光谱的全实验测量、分析和理论支持。在手性分子中发现新的非线性光学指纹,为在圆二色性可能存在强烈限制的区域中识别和理解光学活性系统提供了新的机会。