手性介孔卟啉-硅杂化材料的合成。
Formation of chiral mesostructured porphyrin-silica hybrids.
机构信息
School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai, P R China.
出版信息
Chem Commun (Camb). 2011 Mar 7;47(9):2607-9. doi: 10.1039/c0cc05078d. Epub 2011 Jan 13.
PMID:21234487
Abstract
Formation of a chiral mesostructured porphyrin-silica hybrid with cylindrical helical stacking of anionic porphyrins was achieved by the aid of cationic organosilane. The enantiopurity of the hybrid was dramatically enhanced by a small amount of (R)-1,1'-bi-2-naphthol or its enantiomer.
摘要
手性介孔卟啉-硅杂化材料通过阳离子有机硅烷的辅助作用，实现了阴离子卟啉的圆柱螺旋堆积。少量（R）-1,1'-联-2-萘酚或其对映异构体可以显著提高杂化材料的对映纯度。
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