Laboratório de Bioinorgânica e Cristalografia, Departamento de Química, Universidade Federal de Santa Catarina, Campus Trindade, BR-88040-900 Florianópolis SC, Brazil.
Inorg Chem. 2010 Mar 15;49(6):2580-2. doi: 10.1021/ic902489j.
Presented herein is the synthesis and characterization of a new Fe(III)Zn(II) complex containing a Fe(III)-bound phenolate with a carbonyl functional group, which was anchored to 3-aminopropyl-functionalized silica as the solid support. The catalytic efficiency of the immobilized catalyst in the hydrolysis of 2,4-bis(dinitrophenyl)phosphate is comparable to the homogeneous reaction, and the supported catalyst can be reused for subsequent diester hydrolysis reactions.
本文介绍了一种新型 Fe(III)Zn(II) 配合物的合成与表征，该配合物含有一个与 Fe(III) 配位的带有羰基官能团的酚盐，通过 3-氨丙基功能化的硅胶作为固体载体进行固定。固定化催化剂在 2,4-双（二硝基苯）磷酸酯的水解反应中的催化效率与均相反应相当，并且负载型催化剂可以重复用于后续的二酯水解反应。
