将四硫富瓦烯环化到苝二酰亚胺的海湾区域。
Annulation of tetrathiafulvalene to the bay region of perylenediimide.
机构信息
Departement für Chemie und Biochemie, Universität Bern, Freiestrasse 3, CH-3012 Bern, Switzerland.
出版信息
Org Lett. 2010 Mar 19;12(6):1344-7. doi: 10.1021/ol1002708.
PMID:20170192
Abstract
A tetrathiafulvalene donor has been annulated to the bay region of perylenediimide affording a new pi-conjugated molecular dyad. Various electronic excited charge-transfer states are generated in different oxidation states, leading to almost full absorption in the visible to near-IR region with a high extinction coefficient.
摘要
四噻吩富瓦烯供体已被环合到苝二酰亚胺的酰亚胺区域，得到了一个新的π共轭分子二聚体。不同的氧化态会产生各种电子激发的电荷转移态，导致在可见光到近红外区域具有高消光系数的近乎完全吸收。
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