钯催化 N-对甲苯磺酰腙与芳基硼酸的氧化交叉偶联。
Pd-catalyzed oxidative cross-coupling of N-tosylhydrazones with arylboronic acids.
机构信息
Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China.
出版信息
Chem Commun (Camb). 2010 Mar 14;46(10):1724-6. doi: 10.1039/b925590g. Epub 2010 Feb 3.
DOI:10.1039/b925590g
PMID:20177629
Abstract
The Pd-catalyzed reaction of N-tosylhydrazones and arylboronic acids provides olefin derivatives. This oxidative cross-coupling is suggested to proceed through a migratory insertion process of a Pd carbene intermediate.
摘要
钯催化 N-对甲苯磺酰腙和芳基硼酸的反应提供了烯烃衍生物。这种氧化交叉偶联反应被认为是通过钯卡宾中间体的迁移插入过程进行的。
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