Department of Chemistry, Sambhu Nath College, Labpur, Birbhum-731303, West Bengal, India.
Chem Commun (Camb). 2010 Mar 14;46(10):1754-6. doi: 10.1039/b919937c. Epub 2010 Jan 12.
{[Cu(2)(H(2)L)(OH)(H(2)O)].(ClO(4))(2)(H(2)O)} (1) serves as a selective azide ion fluorescent sensor in aqueous medium. 1 binds with N(3)(-) to give [Cu(6)(HL)(2)(mu(1,1)-N(3))(6)] (2) which imposes rigidity and decreases the non-radiative decay of the excited state to give rise to fluorescent enhancement. 1 is highly selective over other various anions in aqueous medium.
{[Cu(2)(H(2)L)(OH)(H(2)O)].(ClO(4))(2)(H(2)O)}（1）在水相中可用作选择性叠氮离子荧光传感器。1 与 N(3)(-)结合生成 [Cu(6)(HL)(2)(mu(1,1)-N(3))(6)]（2），这增加了刚性并降低了激发态的非辐射衰减，从而导致荧光增强。1 在水相中对其他各种阴离子具有高选择性。
