铂催化的芳基炔烃双硼化反应：1,2-二硼芳基的合成与反应。
Platinum-catalysed diborylation of arynes: synthesis and reaction of 1,2-diborylarenes.
机构信息
Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima 739-8527, Japan.
出版信息
Chem Commun (Camb). 2010 Mar 14;46(10):1763-5. doi: 10.1039/b919407j. Epub 2010 Jan 13.
DOI:10.1039/b919407j
PMID:20177642
Abstract
Arynes are found to be facilely inserted into bis(pinacolato)diboron by using a platinum-isocyanide catalyst, affording diverse 1,2-diborylarenes, which can be converted into o-terphenyls via Suzuki-Miyaura coupling reaction.
摘要
芳基硼酸频哪醇酯在铂-异腈催化剂的作用下容易插入到双(频哪醇)二硼中，得到各种 1,2-二硼芳基化合物，它们可以通过 Suzuki-Miyaura 偶联反应转化为邻三联苯。
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