Chemistry Department, Faculty of Science, M. S. University of Baroda, Vadodara, 390 002, India.
Dalton Trans. 2010 Mar 14;39(10):2615-21. doi: 10.1039/b919021j. Epub 2010 Jan 28.
The catalytic activity of zirconia supported lacunary undecatungstophosphate was evaluated for solvent free oxidation reactions. The catalyst was proved to be successful for clean and green oxidation reactions which can be useful in waste minimization. The superiority of the present catalyst lies, especially, in obtaining 98% conversion of styrene and >99.9% selectivity for benzaldehyde with H(2)O(2). With molecular oxygen the catalyst gives 50% conversion with 70% selectivity towards epoxide in 4 h only.
研究了负载型十二缺位钨磷酸的氧化催化活性，用于无溶剂条件下的氧化反应。该催化剂可用于清洁绿色氧化反应，有助于减少废物的生成。与分子氧相比，该催化剂在 4 h 内仅需 50%的转化率和 70%的环氧化物选择性。
