Polyoxometalate and Catalysis Laboratory, Department of Chemistry, Faculty of Science, The M. S. University of Baroda, Vadodara, 390002, India.
Dalton Trans. 2014 Feb 14;43(6):2512-20. doi: 10.1039/c3dt52395k. Epub 2013 Dec 5.
A new catalyst comprising monolacunary phosphomolybdate and MCM-41 was synthesized and characterized by different physicochemical techniques. The catalytic activity was evaluated by carrying out solvent free aerobic oxidation of alkenes and alcohols. The catalyst showed 60% conversion of styrene and 28% conversion of benzyl alcohol. The superiority of the present catalytic system lies in obtaining better conversion under solvent free and aerobic conditions.
一种由单缺位磷钼酸盐和 MCM-41 组成的新型催化剂通过不同的物理化学技术进行了合成和表征。通过无溶剂有氧氧化烯烃和醇来评价催化活性。该催化剂显示出苯乙烯 60%的转化率和苄醇 28%的转化率。本催化体系的优越性在于在无溶剂和有氧条件下获得更好的转化率。