环状磺酰胺作为通过不寻常的 S(O)2-O 键断裂合成多取代和多取代苯并噻唑烷的载体。
Cyclic sulfamidates as vehicles for the synthesis of poly- and diversely substituted benzosultams via unusual S(O)2-O bond cleavage.
机构信息
Univ Lille Nord de France, F-59000 Lille, France.
出版信息
Org Lett. 2010 Mar 19;12(6):1356-9. doi: 10.1021/ol100288k.
PMID:20180517
Abstract
1,2-Cyclic sulfamidates undergo novel, efficient, and regiospecific intramolecular nucleophilic cleavage with aryllithiated species to provide an entry to poly-, diversely, and enantiopure N-substituted benzosultams.
摘要
1,2-环磺酰胺经历新颖、高效且区域选择性的分子内亲核断裂，与芳基锂物种反应，为合成多取代、多样和对映纯 N-取代苯并噻唑烷提供了途径。
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