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Mechanism of C-F reductive elimination from palladium(IV) fluorides.
J Am Chem Soc. 2010 Mar 24;132(11):3793-807. doi: 10.1021/ja909371t.
2
Electrophilic halogenation-reductive elimination chemistry of organopalladium and -platinum complexes.
Acc Chem Res. 2015 Feb 17;48(2):238-47. doi: 10.1021/ar500325x. Epub 2015 Jan 20.
4
Formation of ArF from LPdAr(F): catalytic conversion of aryl triflates to aryl fluorides.
Science. 2009 Sep 25;325(5948):1661-4. doi: 10.1126/science.1178239. Epub 2009 Aug 13.
5
Bystanding F+ oxidants enable selective reductive elimination from high-valent metal centers in catalysis.
Angew Chem Int Ed Engl. 2011 Feb 11;50(7):1478-91. doi: 10.1002/anie.201005142. Epub 2011 Jan 24.
6
Carbon-fluorine reductive elimination from a high-valent palladium fluoride.
J Am Chem Soc. 2008 Aug 6;130(31):10060-1. doi: 10.1021/ja803187x. Epub 2008 Jul 11.
10
Synthesis and reactivity of palladium(II) fluoride complexes containing nitrogen-donor ligands.
Dalton Trans. 2010 Jan 14(2):632-40. doi: 10.1039/b914426a. Epub 2009 Nov 26.

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1
Enantioselective Pd-Catalysed Nucleophilic C(sp)-H (Radio)fluorination.
Nat Catal. 2025 Jul;8(7):678-687. doi: 10.1038/s41929-025-01366-x. Epub 2025 Jul 14.
2
Sonosynthesis of new functionalized optically active triazines double Mannich reaction: antibacterial potential and docking study.
RSC Adv. 2025 Jun 4;15(22):17516-17534. doi: 10.1039/d5ra01283j. eCollection 2025 May 21.
3
Fluoride-induced redox-switchable behaviour of a palladium(ii)/(iv) couple.
Chem Sci. 2025 Mar 7;16(15):6257-6264. doi: 10.1039/d4sc08203f. eCollection 2025 Apr 9.
4
-selective Cyclopropanation of Nonconjugated Alkenes with Diverse Pronucleophiles via Directed Nucleopalladation.
J Am Chem Soc. 2024 Sep 4;146(35):24503-24514. doi: 10.1021/jacs.4c07039. Epub 2024 Aug 22.
5
Benzylic C(sp)-H fluorination.
Beilstein J Org Chem. 2024 Jul 10;20:1527-1547. doi: 10.3762/bjoc.20.137. eCollection 2024.
6
C-H bond activation concerted metalation-deprotonation at a palladium(iii) center.
Chem Sci. 2023 Mar 13;14(14):3800-3808. doi: 10.1039/d3sc00034f. eCollection 2023 Apr 5.
7
Studying Regioisomer Formation in the Pd-Catalyzed Fluorination of Cyclic Vinyl Triflates: Evidence for in situ Ligand Modification.
Angew Chem Int Ed Engl. 2023 Apr 3;62(15):e202300109. doi: 10.1002/anie.202300109. Epub 2023 Mar 2.
8
Regio- and Stereoselective 1,2-Oxyhalogenation of Non-Conjugated Alkynes via Directed Nucleopalladation: Catalytic Access to Tetrasubstituted Alkenes.
Angew Chem Int Ed Engl. 2022 Oct 24;61(43):e202209099. doi: 10.1002/anie.202209099. Epub 2022 Sep 29.
9
Mechanism of the Aryl-F Bond-Forming Step from Bi(V) Fluorides.
J Am Chem Soc. 2022 Aug 17;144(32):14489-14504. doi: 10.1021/jacs.2c01072. Epub 2022 Aug 3.
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Oxidative Fluorination of Heteroatoms Enabled by Trichloroisocyanuric Acid and Potassium Fluoride.
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本文引用的文献

2
A bonding model for gold(I) carbene complexes.
Nat Chem. 2009 Sep;1(6):482-6. doi: 10.1038/nchem.331.
3
Bimetallic palladium catalysis: direct observation of Pd(III)-Pd(III) intermediates.
J Am Chem Soc. 2009 Dec 2;131(47):17050-1. doi: 10.1021/ja906935c.
4
Transition-metal-mediated reactions for C(sp2)-F bond construction: the state of play.
Angew Chem Int Ed Engl. 2009;48(46):8610-4. doi: 10.1002/anie.200902121.
7
Formation of ArF from LPdAr(F): catalytic conversion of aryl triflates to aryl fluorides.
Science. 2009 Sep 25;325(5948):1661-4. doi: 10.1126/science.1178239. Epub 2009 Aug 13.
8
Fluorination of boronic acids mediated by silver(I) triflate.
Org Lett. 2009 Jul 2;11(13):2860-3. doi: 10.1021/ol901113t.
10
Versatile Pd(OTf)2 x 2 H2O-catalyzed ortho-fluorination using NMP as a promoter.
J Am Chem Soc. 2009 Jun 10;131(22):7520-1. doi: 10.1021/ja901352k.

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