相似文献
1
Mechanism of C-F reductive elimination from palladium(IV) fluorides.钯(IV)氟化物中 C-F 还原消除的机理。
J Am Chem Soc. 2010 Mar 24;132(11):3793-807. doi: 10.1021/ja909371t.
2
Electrophilic halogenation-reductive elimination chemistry of organopalladium and -platinum complexes.有机钯和铂配合物的亲电卤化-还原消除化学。
Acc Chem Res. 2015 Feb 17;48(2):238-47. doi: 10.1021/ar500325x. Epub 2015 Jan 20.
3
The mechanism, electronic and ligand effects for reductive elimination from arylPd(II) trifluoromethyl complexes: a systematic DFT study.芳基钯（II）三氟甲基配合物还原消除的机理、电子及配体效应：一项系统的密度泛函理论研究
Dalton Trans. 2015 Mar 14;44(10):4613-22. doi: 10.1039/c4dt03267e.
4
Formation of ArF from LPdAr(F): catalytic conversion of aryl triflates to aryl fluorides.由LPdAr(F)形成ArF：芳基三氟甲磺酸酯催化转化为芳基氟化物。
Science. 2009 Sep 25;325(5948):1661-4. doi: 10.1126/science.1178239. Epub 2009 Aug 13.
5
Bystanding F+ oxidants enable selective reductive elimination from high-valent metal centers in catalysis.旁观的 F+ 氧化剂能够在催化中使高价金属中心发生选择性还原消除。
Angew Chem Int Ed Engl. 2011 Feb 11;50(7):1478-91. doi: 10.1002/anie.201005142. Epub 2011 Jan 24.
6
Carbon-fluorine reductive elimination from a high-valent palladium fluoride.高价钯氟化物中碳-氟的还原消除反应。
J Am Chem Soc. 2008 Aug 6;130(31):10060-1. doi: 10.1021/ja803187x. Epub 2008 Jul 11.
7
The organometallic fluorine chemistry of palladium and rhodium: studies toward aromatic fluorination.钯和铑的有机金属氟化学：芳香族氟化研究。
Acc Chem Res. 2010 Jan 19;43(1):160-71. doi: 10.1021/ar9001763.
8
Mechanistic and computational studies of oxidatively-induced aryl-CF3 bond-formation at Pd: rational design of room temperature aryl trifluoromethylation.氧化诱导的芳基-CF3 键形成的机理和计算研究：Pd 室温芳基三氟甲基化的合理设计。
J Am Chem Soc. 2011 May 18;133(19):7577-84. doi: 10.1021/ja201726q. Epub 2011 Apr 22.
9
Detailed study of C-O and C-C bond-forming reductive elimination from stable C2N2O2-ligated palladium(IV) complexes.对稳定的C2N2O2配位钯(IV)配合物中C-O和C-C键形成的还原消除的详细研究。
J Am Chem Soc. 2009 Aug 12;131(31):10974-83. doi: 10.1021/ja9014474.
10
Synthesis and reactivity of palladium(II) fluoride complexes containing nitrogen-donor ligands.含氮供体配体的钯（II）氟化物配合物的合成与反应性。
Dalton Trans. 2010 Jan 14(2):632-40. doi: 10.1039/b914426a. Epub 2009 Nov 26.
引用本文的文献
1
Enantioselective Pd-Catalysed Nucleophilic C(sp)-H (Radio)fluorination.对映选择性钯催化的亲核C(sp)-H（放射性）氟化反应。
Nat Catal. 2025 Jul;8(7):678-687. doi: 10.1038/s41929-025-01366-x. Epub 2025 Jul 14.
2
Sonosynthesis of new functionalized optically active triazines double Mannich reaction: antibacterial potential and docking study.新型功能化光学活性三嗪的声合成：双曼尼希反应、抗菌潜力及对接研究
RSC Adv. 2025 Jun 4;15(22):17516-17534. doi: 10.1039/d5ra01283j. eCollection 2025 May 21.
3
Fluoride-induced redox-switchable behaviour of a palladium(ii)/(iv) couple.氟化物诱导的钯（II）/（IV）电对的氧化还原可切换行为。
Chem Sci. 2025 Mar 7;16(15):6257-6264. doi: 10.1039/d4sc08203f. eCollection 2025 Apr 9.
4
-selective Cyclopropanation of Nonconjugated Alkenes with Diverse Pronucleophiles via Directed Nucleopalladation.通过导向性亲核钯化反应实现非共轭烯烃与多种亲核前体的选择性环丙烷化反应
J Am Chem Soc. 2024 Sep 4;146(35):24503-24514. doi: 10.1021/jacs.4c07039. Epub 2024 Aug 22.
5
Benzylic C(sp)-H fluorination.苄基C(sp) -H氟化反应
Beilstein J Org Chem. 2024 Jul 10;20:1527-1547. doi: 10.3762/bjoc.20.137. eCollection 2024.
6
C-H bond activation concerted metalation-deprotonation at a palladium(iii) center.钯（III）中心的C-H键活化协同金属化-去质子化反应。
Chem Sci. 2023 Mar 13;14(14):3800-3808. doi: 10.1039/d3sc00034f. eCollection 2023 Apr 5.
7
Studying Regioisomer Formation in the Pd-Catalyzed Fluorination of Cyclic Vinyl Triflates: Evidence for in situ Ligand Modification.研究 Pd 催化的环状乙烯基三氟甲磺酸酯氟化反应中的区域异构体形成：原位配体修饰的证据。
Angew Chem Int Ed Engl. 2023 Apr 3;62(15):e202300109. doi: 10.1002/anie.202300109. Epub 2023 Mar 2.
8
Regio- and Stereoselective 1,2-Oxyhalogenation of Non-Conjugated Alkynes via Directed Nucleopalladation: Catalytic Access to Tetrasubstituted Alkenes.区域和立体选择性 1,2-卤化非共轭炔烃通过导向的钯络合反应：四取代烯烃的催化方法。
Angew Chem Int Ed Engl. 2022 Oct 24;61(43):e202209099. doi: 10.1002/anie.202209099. Epub 2022 Sep 29.
9
Mechanism of the Aryl-F Bond-Forming Step from Bi(V) Fluorides.从 Bi(V) 氟化物出发的芳基-F 键形成步骤的机理。
J Am Chem Soc. 2022 Aug 17;144(32):14489-14504. doi: 10.1021/jacs.2c01072. Epub 2022 Aug 3.
10
Oxidative Fluorination of Heteroatoms Enabled by Trichloroisocyanuric Acid and Potassium Fluoride.三氯异氰尿酸和氟化钾促进的杂原子氧化氟化反应。
Angew Chem Int Ed Engl. 2022 Aug 1;61(31):e202205088. doi: 10.1002/anie.202205088. Epub 2022 Jun 21.
本文引用的文献
1
Bimetallic Pd(III) complexes in palladium-catalysed carbon–heteroatom bond formation.钯催化碳-杂原子键形成中的双金属 Pd(III) 配合物。
Nat Chem. 2009 Jul;1(4):302-9. doi: 10.1038/nchem.246.
2
A bonding model for gold(I) carbene complexes.金(I)卡宾配合物的成键模型。
Nat Chem. 2009 Sep;1(6):482-6. doi: 10.1038/nchem.331.
3
Bimetallic palladium catalysis: direct observation of Pd(III)-Pd(III) intermediates.双金属钯催化：Pd(III)-Pd(III)中间体的直接观察。
J Am Chem Soc. 2009 Dec 2;131(47):17050-1. doi: 10.1021/ja906935c.
4
Transition-metal-mediated reactions for C(sp2)-F bond construction: the state of play.用于构建C(sp2)-F键的过渡金属介导反应：进展状况
Angew Chem Int Ed Engl. 2009;48(46):8610-4. doi: 10.1002/anie.200902121.
5
The organometallic fluorine chemistry of palladium and rhodium: studies toward aromatic fluorination.钯和铑的有机金属氟化学：芳香族氟化研究。
Acc Chem Res. 2010 Jan 19;43(1):160-71. doi: 10.1021/ar9001763.
6
On the impact of steric and electronic properties of ligands on gold(I)-catalyzed cycloaddition reactions.关于配体的空间和电子性质对金（I）催化环加成反应的影响
Org Lett. 2009 Nov 5;11(21):4798-801. doi: 10.1021/ol9018002.
7
Formation of ArF from LPdAr(F): catalytic conversion of aryl triflates to aryl fluorides.由LPdAr(F)形成ArF：芳基三氟甲磺酸酯催化转化为芳基氟化物。
Science. 2009 Sep 25;325(5948):1661-4. doi: 10.1126/science.1178239. Epub 2009 Aug 13.
8
Fluorination of boronic acids mediated by silver(I) triflate.三氟甲磺酸银（I）介导的硼酸氟化反应。
Org Lett. 2009 Jul 2;11(13):2860-3. doi: 10.1021/ol901113t.
9
Detailed study of C-O and C-C bond-forming reductive elimination from stable C2N2O2-ligated palladium(IV) complexes.对稳定的C2N2O2配位钯(IV)配合物中C-O和C-C键形成的还原消除的详细研究。
J Am Chem Soc. 2009 Aug 12;131(31):10974-83. doi: 10.1021/ja9014474.
10
Versatile Pd(OTf)2 x 2 H2O-catalyzed ortho-fluorination using NMP as a promoter.使用NMP作为促进剂的通用Pd(OTf)₂·2H₂O催化邻位氟化反应。
J Am Chem Soc. 2009 Jun 10;131(22):7520-1. doi: 10.1021/ja901352k.
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