（±）-aspercyclide A 及其 C19 甲醚的全合成。
Total synthesis of (+/-)-aspercyclide A and its C19 methyl ether.
机构信息
Department of Chemistry, South Kensington campus, Imperial College, London, UK SW7 2AZ.
出版信息
Chem Commun (Camb). 2010 Mar 21;46(11):1824-6. doi: 10.1039/b923528k. Epub 2009 Dec 23.
DOI:10.1039/b923528k
PMID:20198221
Abstract
The total syntheses of (+/-)-aspercyclide A (1) and its C19 methyl ether (15a) featuring Heck-Mizoroki macrocyclisation to form the 11-membered (E)-styrenyl biaryl ether lactone core are described.
摘要
本文描述了 (+/-)-aspercyclide A（1）及其 C19 甲醚（15a）的全合成，其中包括 Heck-Mizoroki 大环化反应，形成 11 元（E）-苯乙烯基联芳基醚内酯核心。
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