互补的卤素和氢键：硫……碘相互作用和硫代酰胺带。
Complementary halogen and hydrogen bonding: sulfur...iodine interactions and thioamide ribbons.
机构信息
Department of Chemistry, Clemson University, Clemson, SC, USA.
出版信息
Chem Commun (Camb). 2010 Mar 21;46(11):1854-6. doi: 10.1039/b925710a. Epub 2010 Feb 12.
DOI:10.1039/b925710a
PMID:20198231
Abstract
Complementary halogen bonding and hydrogen bonding coexist in co-crystals of organoiodines with molecules containing the thioamide functionality. Thiourea.organoiodine co-crystals are shown to exhibit a remarkably reliable synthon with complementary N-H...S ribbons and S...I interactions.
摘要
有机碘化物与含硫酰胺官能团的分子形成的共晶中存在互补的卤素键和氢键。硫脲.有机碘共晶表现出一种非常可靠的具有互补的 N-H...S 带状结构和 S...I 相互作用的亚单元。
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