锡(II)双(膦酰基)甲烷二酰亚胺配合物的合成与表征：一种锡烯基衍生物。
Synthesis and characterization of a tin(II) bis(phosphinoyl)methanediide complex: a stannavinylidene derivative.
机构信息
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371 Singapore.
出版信息
Chem Commun (Camb). 2010 Mar 21;46(11):1929-31. doi: 10.1039/b922377k. Epub 2010 Feb 9.
DOI:10.1039/b922377k
PMID:20198256
Abstract
The reaction of [CH(2)(PPh(2)=NSiMe(3))(PPh(2)=S)] (1) with two equivalents of [Sn{N(SiMe(3))(2)}(2)] in refluxing toluene afforded novel tin(II) bis(phosphinoyl)methanediide complex 3. The structure of compound 3 has been determined by X-ray crystallography and DFT calculations. The topological analysis of the electron densities of compound 3 was performed.
摘要
[CH(2)(PPh(2)=NSiMe(3))(PPh(2)=S)]（1）与两当量的[Sn{N(SiMe(3))(2)}(2)]在回流的甲苯中反应，得到了新型锡（II）双（膦酰基）甲烷二化物配合物 3。通过 X 射线晶体学和 DFT 计算确定了化合物 3 的结构。对化合物 3 的电子密度进行了拓扑分析。
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