Lehrstuhl für Anorganische Chemie II der Technischen Universität Dortmund, D-44221 Dortmund, Germany.
Inorg Chem. 2011 Sep 5;50(17):8645-53. doi: 10.1021/ic201203u. Epub 2011 Jul 29.
The syntheses and molecular structures of the intramolecularly coordinated tin(II) compounds {CH(2)N(Me)CH(Me)CH(Ph)O}(2)SnL (2, L = lone pair; 4, L = W(CO)(5); 5, L = Cr(CO)(5)) and of the related hydroxido-substituted tin(IV) compound {CH(2)N(Me)CH(Me)CH(Ph)O}(2)Sn(OH)O, 6a, are reported. Also reported are the molecular structures of the enantiopure N,N'-ethylenebis-(1R,2S)-ephedrine, {CH(2)N(Me)CH(Me)CH(Ph)OH}(2) (1), and its hydrobromide {CH(2)N(Me)CH(Me)CH(Ph)OH}(2)·HBr (1a).
报道了分子内配位的锡（II）化合物{CH(2)N(Me)CH(Me)CH(Ph)O}(2)SnL（2，L=孤对电子；4，L=W(CO)(5)；5，L=Cr(CO)(5)）和相关的羟基取代的锡（IV）化合物{CH(2)N(Me)CH(Me)CH(Ph)O}(2)Sn(OH)O，6a 的合成和分子结构。还报道了对映纯的 N，N'-亚乙基双（1R，2S）-麻黄碱，{CH(2)N(Me)CH(Me)CH(Ph)OH}(2)（1）及其氢溴酸盐{CH(2)N(Me)CH(Me)CH(Ph)OH}(2)·HBr（1a）的分子结构。
