Wu Gui-Fang, He Yong
College of Biosystems Engineering and Food Science, Zhejiang University, Hangzhou 310029, China.
Guang Pu Xue Yu Guang Pu Fen Xi. 2009 Dec;29(12):3246-9.
Aimed at noise interference of infrared spectra, an example of using infrared spectra to detect fat content value on the surface of cashmere was applied to evaluate the effect of wavelet threshold denoising. The denoising capabilities of three wavelet threshold denoising models (penalty threshold denoising model, Brige-Massart threshold denoising model and default threshold denoising model) were compared and analyzed. Denoised spectra and measured cashmere fat content values were used for calibration and validation with multivariate analysis (partial least squares combined with support vector machine). The authors analyzed and evaluated denoising effects of these three wavelet threshold denoising models by comparing parameters (R2, RMSEC and RMSEP) obtained through calibration and validation of denoised spectra with these three wavelet threshold denoising models respectively. The results show that the three wavelet threshold denoising models all can denoise the infrared spectral signal, increase signal to noise ratio and improve precision of prediction model to some extent; Among these three wavelet threshold denoising models, the denoising effect of Brige-Massart threshold denoising model and default threshold denoising model were significantly better than that of default threshold denoising model; Compared with the prediction precision (R2 = 0.793, RMSEC = 0.233, RMSEP = 0.225) of multivariate analysis model established with original spectra, the prediction precision (R2 = 0.882, RMSEC = 0.144, RMSEP = 0.136) of multivariate analysis model established with spectra denoised by Brige-Massart threshold denoising model and the prediction precision (R2 = 0.876, RMSEC = 0.151, RMSEP = 0.142) both had much more improvements. All the above illustrates that wavelet threshold denoising models can denoise infrared spectral signal effectively, make multivariate analysis model of spectral data and measured cashmere fat values more representative and robust, and so it can improve detection precision of infrared spectral technique.
针对红外光谱的噪声干扰问题,以利用红外光谱检测羊绒表面脂肪含量值为例,对小波阈值去噪效果进行评估。比较并分析了三种小波阈值去噪模型(惩罚阈值去噪模型、Brige - Massart阈值去噪模型和默认阈值去噪模型)的去噪能力。将去噪后的光谱和实测羊绒脂肪含量值用于多元分析(偏最小二乘法结合支持向量机)的校准和验证。作者通过比较分别用这三种小波阈值去噪模型对光谱进行校准和验证所得到的参数(R2、RMSEC和RMSEP),对这三种小波阈值去噪模型的去噪效果进行分析和评估。结果表明,三种小波阈值去噪模型均能对红外光谱信号进行去噪,提高信噪比,并在一定程度上提高预测模型的精度;在这三种小波阈值去噪模型中,Brige - Massart阈值去噪模型和默认阈值去噪模型的去噪效果明显优于惩罚阈值去噪模型;与用原始光谱建立的多元分析模型的预测精度(R2 = 0.793,RMSEC = 0.233,RMSEP = 0.225)相比,用Brige - Massart阈值去噪模型去噪后的光谱建立的多元分析模型的预测精度(R2 = 0.882,RMSEC = 0.144,RMSEP = 0.136)以及默认阈值去噪模型去噪后的光谱建立的多元分析模型的预测精度(R2 = 0.876,RMSEC = 0.151,RMSEP = 0.142)均有较大提高。上述所有结果表明,小波阈值去噪模型能够有效去除红外光谱信号中的噪声,使光谱数据与实测羊绒脂肪含量值的多元分析模型更具代表性和稳健性,从而提高红外光谱技术的检测精度。