布克霍尔德氏菌属中腺嘌呤核苷酸转位酶（ATPase）抑制剂邦克来酸的生物合成。
Biosynthesis of the mitochondrial adenine nucleotide translocase (ATPase) inhibitor bongkrekic acid in Burkholderia gladioli.
机构信息
Leibniz Institute for Natural Product Research and Infection Biology, HKI, Beutenbergstr. 11a, D-07745 Jena, Germany.
出版信息
Org Biomol Chem. 2010 Apr 7;8(7):1520-2. doi: 10.1039/b925483h. Epub 2010 Feb 5.
DOI:10.1039/b925483h
PMID:20237660
Abstract
Biosynthetic studies with (13)C-labelled acetates and methionine revealed that the infamous, food-related toxin bongkrekic acid from Burkholderia gladioli is a polyketide with acetate-derived beta-branches and a carboxylate terminus derived from the methyl group of an acetate.
摘要
利用 (13)C 标记的乙酸盐和蛋氨酸进行的生物合成研究表明，来自恶臭假单胞菌的臭名昭著的与食物有关的毒素棒曲霉素是一种聚酮化合物，具有来自乙酸盐的β支链和来自乙酸盐的甲基的羧酸盐末端。
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