Department of Electrical Engineering, Center for Solar Nanomaterials, The Pennsylvania State University, University Park, Pennsylvania 16802, USA.
ACS Nano. 2010 Mar 23;4(3):1253-8. doi: 10.1021/nn100422a.
It appears that the efficiency of dye-sensitized solar cells (DSSCs) has reached a ceiling due to the limited absorption spectrum of currently available dyes. To achieve new record efficiencies, light absorption must be extended into the near-infrared region of the spectrum without sacrificing performance in the visible region. No single dye has this ability, but there is greater strength in numbers. Forster resonance energy transfer (FRET) may be used to link two or more materials to provide strong absorption across a broad portion of the solar spectrum. This process has been shown to be effective and efficient, and a recent breakthrough in FRET-enhanced DSSCs is presented in this issue. This Perspective explores the background of this topic and considers directions for future development.
看来,由于目前可用染料的吸收光谱有限,染料敏化太阳能电池(DSSC)的效率已经达到了一个上限。为了实现新的记录效率,必须将光吸收扩展到光谱的近红外区域,而不会牺牲可见光区域的性能。没有单一的染料具有这种能力,但数量越多,力量就越大。Förster 共振能量转移(FRET)可用于连接两种或更多种材料,以在太阳光谱的较宽部分提供强吸收。已经证明该过程是有效和高效的,本期杂志中介绍了 FRET 增强型 DSSC 的最新突破。本观点探讨了该主题的背景,并考虑了未来发展的方向。