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聚醚醚酮复合材料的制备与摩擦学性能。

Preparation and tribological properties of polyetheretherketone composites.

机构信息

Department of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing, Jiangsu, China.

出版信息

J Biomed Mater Res B Appl Biomater. 2010 May;93(2):492-6. doi: 10.1002/jbm.b.31607.

Abstract

Polyetheretherketone (PEEK) is a thermoplastic engineering plastic with excellent mechanical properties. In this article, PEEK and its composites filled with ultrahigh-molecular-weight polyethylene (UHMWPE) were prepared by vacuum hot-pressing method. Tribological properties of these materials were investigated by block-on-ring friction and wear rig. An alloy (CoCrMo) ring and a ceramic (Si(3)N(4)) ring were used as friction pairs. The experiments were conducted under deionized water lubrication (DWL), saline lubrication (SL), and calf serum solution lubrication (CSSL). Worn surfaces morphology was observed and analyzed by metallographic microscope. The results indicated that friction coefficients of PEEK/UHMWPE composites were effectively reduced when compared with pure PEEK. When the materials slid against the alloy (CoCrMo) ring, wear rates of PEEK/UHMWPE were also effectively reduced when compared with pure PEEK. Wear mechanisms of PEEK were mainly ploughing and slight scratches under CSSL condition, whereas the quantity of the ploughing and scratches for PEEK/20%UHMWPE were significantly reduced.

摘要

聚醚醚酮(PEEK)是一种具有优异机械性能的热塑性工程塑料。本文采用真空热压法制备了超高分子量聚乙烯(UHMWPE)填充的 PEEK 及其复合材料。采用块环式摩擦磨损试验机研究了这些材料的摩擦学性能。采用合金(CoCrMo)环和陶瓷(Si(3)N(4))环作为摩擦副。在去离子水润滑(DWL)、盐水润滑(SL)和小牛血清溶液润滑(CSSL)下进行了实验。用金相显微镜观察和分析了磨损表面形貌。结果表明,与纯 PEEK 相比,PEEK/UHMWPE 复合材料的摩擦系数得到了有效降低。当材料与合金(CoCrMo)环滑动时,与纯 PEEK 相比,PEEK/UHMWPE 的磨损率也得到了有效降低。在 CSSL 条件下,PEEK 的磨损机制主要是犁耕和轻微划痕,而 PEEK/20%UHMWPE 的犁耕和划痕数量明显减少。

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