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聚氨酯/聚乙二醇/铜纳米复合材料的制备与表征

[Preparation and characterization of polyurethane/polyethylene glycol/copper nanocomposite].

作者信息

Xu Yufang, Wang Jue, Chen Yongjun, Chen Juan, Jia Demin, Zhong Xingming, Miao Zhulin, Wei Xiangcai

机构信息

IInstitute of Family Planning of Guangdong Province, Guangzhou 510060, China.

出版信息

Sheng Wu Yi Xue Gong Cheng Xue Za Zhi. 2010 Feb;27(1):102-8.

Abstract

A novel Cu-IUDs material, PU/PEG/Cu nanocomposite, was prepared by melt blending method with thermoplastic polyurethane (PU) as the matrix, with polyethylene glycol (PEG) as a hydrophilic modifier, and with nanometer particles of copper as active matter instead of copper wire or copper tube. The structure, morphology, mechanical properties, thermal stability and water absorption were investigated by using FT-IR, XRD, SEM and so on. The results indicated that the nanometer particles of copper were uniformly dispersed in the matrix in PU/PEG/ Cu nanocomposites. It can be seen that the water absorption ability of this nanocomposite was obviously improved while mechanical properties and thermal stability were at high levels. These results provided a good basis for the studies on the cupric ions release of the nanocomposites in future.

摘要

一种新型的宫内节育器(IUDs)材料——聚氨酯/聚乙二醇/铜(PU/PEG/Cu)纳米复合材料,通过熔融共混法制备而成,该材料以热塑性聚氨酯(PU)为基体,聚乙二醇(PEG)为亲水性改性剂,以纳米铜颗粒作为活性物质替代铜丝或铜管。利用傅里叶变换红外光谱(FT-IR)、X射线衍射(XRD)、扫描电子显微镜(SEM)等对其结构、形态、力学性能、热稳定性及吸水性进行了研究。结果表明,在PU/PEG/Cu纳米复合材料中,纳米铜颗粒均匀分散于基体中。可以看出,该纳米复合材料的吸水能力明显提高,同时力学性能和热稳定性保持在较高水平。这些结果为今后研究纳米复合材料中铜离子的释放提供了良好的基础。

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